Hydrogen environment embrittlement

Hydrogen embrittlement is classified into three types: internal reversible hydrogen embrittlement, hydrogen reaction embrittlement, and hydrogen environment embrittlement. Characteristics of and materials embrittled by these types of hydrogen embrittlement are discussed. Hydrogen environment embrittlement is reviewed in detail. Factors involved in standardizing test methods for detecting the occurrence of and evaluating the severity of hydrogen environment embrittlement are considered. The effect of test technique, hydrogen pressure, purity, strain rate, stress concentration factor, and test temperature are discussed. Additional research is required to determine whether hydrogen environment embrittlement and internal reversible hydrogen embrittlement are similar or distinct types of embrittlement

Hydrogen embrittlement susceptibility of a high strength steel X80

The present paper deals with hydrogen embrittlement (HE) susceptibility of a high strength steel grade (X80). The respective implication of different hydrogen populations, i.e. adsorbed, dissolved in interstitial sites, trapped on dislocations and/or microstructural elements on the associated embrittlement mechanisms has been addressed through mechanical testing in high pressure of hydrogen gas at room temperature. Tensile tests at various strain rates and hydrogen pressures have been carried out. Moreover, changes of gas (hydrogen or nitrogen) during loading have been imposed in order to get critical experiments able to discriminate among the potential hydrogen embrittlement mechanisms already proposed in the literature. The results of these tests have shown that hydrogen induces several kind of damages including decohesion along ferrite/pearlite interfaces and microcracks initiations on the specimens external surface. It is shown that decohesion is not critical under the loading paths used in the present study. On the contrary, it appears that the external microcracks initiation, followed by a quasi-cleavage fracture, is responsible for the premature failure of the material in high pressure of hydrogen gas. These experimental results have been further discussed by modeling hydrogen diffusion in order to identify hydrogen populations (adsorbed, diffusible or trapped) involved in HE. It was then demonstrated that adsorbed and near surface diffusible hydrogen are mainly responsible for embrittlement

Potential structural material problems in a hydrogen energy system

Potential structural material problems that may be encountered in the three components of a hydrogen energy system - production, transmission/storage, and utilization - were identified. Hydrogen embrittlement, corrosion, oxidation, and erosion may occur during the production of hydrogen. Hydrogen embrittlement is of major concern during both transmission and utilization of hydrogen. Specific materials research and development programs necessary to support a hydrogen energy system are described

Evaluation of test procedures for hydrogen environment embrittlement

Report presents discussion of three common and primary influences on embrittlement process. Application of theoretical considerations to design of test coupons and methods is illustrated for both internal and external hydrogen embrittlement. Acceptable designs and methods are indicated

Study to minimize hydrogen embrittlement of ultrahigh-strength steels

Hydrogen-stress cracking in high-strength steels is influenced by hydrogen content of the material and its hydrogen absorption tendency. Non-embrittling cleaning, pickling, and electroplating processes are being studied. Protection from this hydrogen embrittlement is important to the aerospace and aircraft industries

Hydrogen environment embrittlement of astroloy and Udimet 700 (nickel-base) and V-57 (iron-base) superalloys

The sensitivity to hydrogen environment embrittlement of three superalloys was determined. Astroloy forgings were resistant to embrittlement during smooth tensile, notched tensile, and creep testing in 3.5-MN/sq m hydrogen over the range 23 to 760 C. The notched tensile strength of Udimet 700 bar stock in hydrogen at 23 C was only 50 percent of the baseline value in helium. Forgings of V-57 were not significantly embrittled by hydrogen during smooth tensile testing over the range 23 to 675 C; creep and rupture lives of V-57 were degraded by hydrogen. Postcreep tensile ductility of V-57 was reduced by 40 percent after creep exposure in hydrogen

Hydrogen embrittlement in bearing steels

Hydrogen embrittlement is, and has been for over a century, a prominent issue within many sectors of industry. Despite this, the mechanisms by which hydrogen embrittlement occur and the suitable means for its prevention are yet to be fully established. Hydrogen embrittlement is becoming an ever more pertinent issue. This has led to a considerable demand for novel hydrogen embrittlement-resistant alloys, notably within the bearings industry. This paper provides an overview of the literature surrounding hydrogen embrittlement in bearing steels, and the means by which manufacturers may optimise alloys and accompanying processes to prevent embrittlement. Notably, novel steels combining both high strength and hydrogen embrittlement resistance are reviewed with respect to their design, evaluation methods and required future work. This paper is part of a Themed Issue on Recent developments in bearing steels

Effects of hydrogen on ELI titanium alloy Ti-5Al-2.5Sn

Tensile tests on titanium alloy, following abrasion under hydrogen and temperature cycling, reveal lowered tensile strength, increased ductility, and no embrittlement. Fretting the metal on itself in flowing hydrogen or abrading with an iron file in flowing hydrogen produces titanium hydride

Susceptibility of irradiated steels to hydrogen embrittlement

Investigation determined whether irradiated pressure-vessel steels 4340 and 212-B are susceptible to hydrogen embrittlement and to catastrophic failure. Hydrogen-charging conditions which completely embrittled 4340 steel had negligible effect on 212-B steel in tensile and delayed-failure tests